Actually, this will probably not give much of a Caapi feel to it for a few reasons.
1) rue contains a couple of rather nasty alkaloids such as Vasicinone and Vasicine. These alkaloids give that "toxic" feeling. adding THH won't take that away from the mix
2) Harmaline, Rue has loads of this alkaloid, Caapi has little to none. It changes the feel quite a bit. Harmaline is quite sedating.
The vine just has its own feel and personallity. If you want to get the feel of Caapi, just use Caapi.
I imagine that adding THH to rue will give it a different feel, but don't expect it to be the same as the vine.
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