Well, they do separate if a good amount of salt (any water-soluble simple salt) is dumped in the water-alcohol mixture. And they do form layers, one can see the interphase between them, alcohol floating on top of water.
But separation is NEVER perfect; the bottom layer will contain some water saturated with salt and traces of alcohol, the top layer will be alcohol with a good amount of water.
Totally useless therefore, since they cannot separate completely.
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