If you describe briefly and sequentially with chems/volumes/times/# of pulls involved we can pin it down.
A small point on terminology which will make your future posts clearer - generally, here folks use "vaporize" to refer to "smoking" spice, and "evaporate" to refer to solvents.
Heptane is a great non-polar solvent, naphtha is good too and slightly broader spectrum (will pull a broader range of alkaloids)... In SWiM's experience freeze precipitation works stunningly with both - slap that next pull in the freezer for 12+ hrs and if the Deemster is present, crystals will crash out, so to speak!
good luck,
L
"The first principle is that you must not fool yourself, and you are the easiest person to fool." Richard P. Feynman