The 40º thing is a common misprint, it boils at that temperature only under a very, Very, VERY strong vacuum. Dangerously strong.
At 0.6 Torr DMT boils at 160º, at 20 times higher pressure water boils at 0º. The air your breathing is 1267 times higher pressure.
This is why you dont ever see anyone distilling DMT, you might as well be distilling asphalt