Personally, I think the combo is just great if the 5-MeO takes the backseat to color the NN-DMT trip in ratios varying between 1:4 or 1:5 (or even higher, depending on how you react to 5-MeO.)
Essentially, 5-MeO at these low doses acts like an empathogen, and makes the DMT experience more physical / euphoric, and (if there's a sweet spot of 5-MeO-DMT blended to really stoke the synergistic flames) can provide a very crystalline perfectness to the clutter/ of DMT hyperspace. Makes the "zany" just a bit more "zen".
Tread carefully however...I'm seriously talking about 3-5 mg's (from either compound,) completely changing the characteristics of the trip. Even less I'll bet.
Unfortunately, I must admit my NN ratios are a bit guesstimated, as I'm using a charged liquid pad - so any fresh material I go through still has whatever is in the pad to work with once it's been freebased. Please take this into consideration as well, that my NN-DMT ratios are high if anything (definitely not short.).
For that reason alone, I might have to make myself a 5-MeO leaf blend (perhaps even just one or two big release doses, no NN-DMT,) because although I've never re-enacted the Exorcist under 5-MeO, I can see the potential lingering in the methoxy high. If the sailor's of yore had sirens - I think 5-MeO has the potential to be our psychedelic siren. ("So beautiful, I just want to hear her song a little closer...CRAAASSHHH!!!!"
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"The most merciful thing in the world, I think, is the inability of the human mind to correlate all its contents." -lovecraft