Oh shute, one morning i woke up to a small catastrophy, feeling active i had done some work late at night after a bottle o wine (won't do that again for sure, so please dont feel the need to point that out, work is done sober) and must have accidently combined a concentrated dmt holding ~10% aceitic acid flask with one from my Rue Extraction from the day before. I was shocked. Now i'm wondering what would be the best way to seperate the alkaloids...

Either via pKa or via Manske, or via NP Solvent i figured, so a lot of questions arose:
If Harmaloids precipitate earlier than dmt, one could try to hit the point in between while basifying, filter the crystals for a raw seperation like in the rue teks. But the pKa numbers are 7.7 (Harmine) - 8.8 (DMT) - 9.8 (Haraline) so dmt is in the middle of an allready thin line (assuming one has no digital pH Meter, only strips) to realize and a lot of work.
If I understand the teks right, haramaloids precipitate in cold NaCl-saturatet acidic-aquaeous-solution, so one could try to then decant the acidic water with the dmt BUT i fear that the dmt will somehow stick to the Harmaloid Alks or solidify itself.
Last but not least, i found myself hoping that maybe, just maybe, no rue-inhabiting substance would migrate into the naphtha. In that case i would base to pH 14 and do normal pulls.

Thanks for your help

Easier to just base it and pull with naphtha or similar non polar, which will not dissolve harmalas. Repeat a few times. Then just filter to retrieve harmalas.

Do a manske on the harmaloids/dmt solution after dissolving in water with an acid, then collect harmaloid hcl alkaloids, and basify water.

Pull with you choice of nps, and salt/freeze-x as you so choose.