Don't worry about the lack of formal chemistry education! Most of us (me included) have had no formal chem education and learned everything through constant surfing the Nexus, practicing with extraction chemistry and general curiosity researching the topics of interest out there
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I highly suggest you read the FAQ if you haven't yet, it's definitely a good starting point for a lot of these questions you might have.
5-MeO-DMT is more potent by weight than DMT, yes, but believe me that doesn't really mean anything, because with any of these substances you are already reaching the limits of what human consciousness can experience and will already leave you grasping for answers like a drowning man grasps for air, you don't need to find anything 'stronger'
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Different DMT 'analogues' such as 5-MeO-DMT and 5-HO-DMT (bufotenine), appart frmo DMT itself of course, are naturally occuring and can in theory be extracted from different plants/life forms.. They are found even in our own bodies in trace amounts... That being said, they could also be synthesized, but here in the Nexus we generally don't talk about those synthesis since they can involve watched chems or dangerous proceedures. We also don't talk about 'sourcing' these compounds here, check our attitude page for more info
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Ayahuasca is a good starting point if you feel called to it
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Do your research, brew it properly and take it in appropriate dosage, set and setting, all should be good. I suggest first time having a sitter or taking with someone experienced, or if neither of those are possible, start with very low doses and raise gradually.
It doesn't have to be a either-or' decision, you can also simultaneously be investing your investigation efforts towards extracting DMT, and trying that out vaporized with a propper vaporization method and appropriate dosage.
Be sure to let us know about your development with these substances, and feel free to ask any questions that a small research with the FAQ and the forum in general doesn't answer you already
Be well!