inorgaic salts are generally more soluble in polar solvents
than nonpolar solvents
and it will no longer be aluminum chloride once you basify.
you'll have several ionic species in solution, and of course, charged
particles do not migrate into nonpolar solvents.
"Nothing is true, everything is permitted." ~ hassan i sabbah
"Experiments are the only means of attaining knowledge at our disposal. The rest is poetry, imagination." -Max Planck