If you live in the US, you might gonna have a bad time. However, if you live in the Europe, the UN Convention on Psychotropic Substances is very clear on this:
"The cultivation of plants from which psychotropic substances are obtained is not controlled by the Vienna Convention. . . . Neither the crown (fruit, mescal button) of the Peyote cactus nor the roots of the plant Mimosa hostilis nor Psilocybe mushrooms themselves are included in Schedule 1, but only their respective principals, mescaline, DMT and psilocin."
Now, they have found a way around this on Psilocybin mushrooms, but ayahuasca plants are still unregulated. So, if you're European, enjoy it while it lasts.
I would like to provide you data for other countries, such as Asian countries and Australia, but I really know nothing.
Edit: Still, if you import small quantities, such as kilo or two, they're not going to bat an eye. If you import really much, they'll probably get interested.
Peace and love.
