Lots of vaping experience here but never did a ceremony (I'm assuming you mean the true Amazon jungle one). Definitely considering it sometime in the future tough...
First of all oral DMT last longer, a true long journey into your mind. Vaping is more of a roller-coaster ride. It's most of the time too short to be able to truly reflect. Intensity wise they can both get extremely intense, all down to dosage.
During the ceremony you can experience purge, which is important to some as it's supposed to cleanse the body and mind. I personally don't even like the thought of a purge at all (bad stomach). Pharmaceutical MAOI can help you avoid purging (Moclobemide). Google pharmahuasca term.
Just keep in mind that a proper ceremony is much more demanding than a simple vaping session. A lot of preparation, travel and it's not just sweets and roses. Many ppl meet their darkest demons during these ceremonies. Make sure to read a lot about the specific retreat you intend to use. There are a lot of dishonest shamans out there. I've read reports about being mugged, shaman raping a woman etc. It's become a business of sorts with increased interest from 'Westerners' and money attracts all kinds of characters... Life.
Watch this for starters and check out the other suggestions that YT will send your way.
https://www.youtube.com/watch?v=dz0XLVUq3WIBe inquisitive and always question things...